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Applications
Two broad applications
have been developed for the ims 1270, a large-radius, triple-focusing
mass spectrometer: U-Th-Pb measurements of accessory minerals, and stable
isotopic analysis of insulators.
U-Th-Pb
analysis U-Th-Pb analysis is conducted using a beam of negative
oxygen ions that can be focused to spots from 1 to 30 µm on 1"
polished thin sections or grain mounts. A slit-lens transfer optical system
and the 585mm radius magnet achieve high secondary ion transmission at
the mass resolving power of ~5,000 required for these analyses. Isotopic
ratios are measured by rapid peak-switching in to a pulse-counting electron
multiplier. Measurements of U-Th-Pb systematics of zircon [e.g. X. Quidelleur
et al., The thermal evolution and slip history of the Renbu Zedong Thrust,
southeastern Tibet. J. Geophys. Res. 1997] and monazite [e.g., Harrison
et al., Earth Planet. Sci. Lett. 133, 271, 1995] yield high Pb sensitivities
(up to 20 cps/ppm/Pb/nA) and typical age accuracy of ±2%.
Oxygen
and Carbon Stable Isotope Analysis Stable isotope measurements
of oxygen and carbon in insulating specimens are undertaken using a Cs+
primary beam which can be focused to a diameter between 0.2 and 30µm.
Carbonates and silicates, for example, have yielded typical delta 18O
precisions of 1.0 per mil for 10 min analysis times and, typically, 15µm
diameter analysis areas [e.g. L.A. Leshin et al., The oxygen isotopic
composition of olivine and pyroxene from CI chondrites. Geochim. Cosmchim.
Acta 1997 (in press)]. The same precision has been obtained for delta
13C in carbonates under similar analytical conditions.
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